Differences between Li-ion and NiCad

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Li-ion vs. NiCad Batteries[edit]

Lithium-ion (Li-ion) and Nickel-Cadmium (NiCad) are both types of rechargeable batteries.[1][2] Li-ion batteries are a newer technology, having been commercialized in the 1990s, and have become the standard for most consumer electronics.[3] NiCad batteries, invented in 1899, are an older, more established technology often used in power tools and emergency lighting.[4][5] The fundamental difference between them lies in their chemistry, which in turn affects their performance characteristics such as energy density, memory effect, and environmental impact.

Comparison Table[edit]

Category Li-ion NiCad
Chemistry Uses lithium ions that move between a graphite anode and a lithium metal oxide cathode.[4][3] Uses nickel oxide hydroxide for the positive electrode (cathode) and metallic cadmium for the negative electrode (anode).[1]
Energy Density Higher energy density, typically ranging from 150-250 Wh/kg.[3] This allows for smaller and lighter batteries. Lower energy density, around 40-80 Wh/kg.[3] Batteries are generally bulkier for the same capacity.[4][2]
Memory Effect Not susceptible to the memory effect. Prone to the memory effect, where partially discharging before recharging can reduce the battery's effective capacity.
Self-Discharge Rate Low self-discharge rate, typically 1-3% per month. Higher self-discharge rate, can be around 10-20% per month.
Cycle Life Generally offers 500-3000 charge cycles.[3] Can provide 500-1000+ charge cycles with proper maintenance.[4]
Cost Higher manufacturing cost, in part due to materials like cobalt and lithium and the need for a protection circuit.[4] Generally less expensive to produce than Li-ion batteries.
Environmental Impact Considered less environmentally harmful as it does not contain cadmium. However, the mining of lithium and cobalt has environmental consequences.[4] Contains cadmium, a toxic heavy metal, which poses significant environmental hazards if not disposed of properly.
Operating Temperature More sensitive to high temperatures, which can accelerate degradation.[4] Can operate over a wide temperature range, often from -20°C to 60°C.
Venn diagram for Differences between Li-ion and NiCad
Venn diagram comparing Differences between Li-ion and NiCad


References[edit]

  1. 1.0 1.1 "wikipedia.org". Retrieved November 24, 2025.
  2. 2.0 2.1 "tsfx.edu.au". Retrieved November 24, 2025.
  3. 3.0 3.1 3.2 3.3 3.4 "tritekbattery.com". Retrieved November 24, 2025.
  4. 4.0 4.1 4.2 4.3 4.4 4.5 4.6 "holobattery.com". Retrieved November 24, 2025.
  5. "rfcafe.com". Retrieved November 24, 2025.